The Layered Semiconductor Cu(Sb2S3)[AlCl4]
نویسندگان
چکیده
Abstract Sb 2 S 3 and CuCl were reacted in the ionic liquid [BMIm]Cl ⋅ 4.4AlCl (BMIm=1‐ n ‐butyl‐3‐methylimidazolium) at 200 °C. Upon cooling to room temperature, orange‐red colored, air‐sensitive crystals of Cu(Sb )[AlCl 4 ] precipitated. X‐ray diffraction on a single‐crystal revealed an orthorhombic crystal structure, which cationic [Cu(Sb )] + layers are separated by tetrahedral [AlCl − anions. The uncharged partial structure consists one‐dimensional strands with covalent Sb−S single bonds. copper(I) cation is coordinated three sulfur atoms one chlorine – anion. An optical band gap 2.14 eV was deduced from UV/Vis spectra. In very good agreement, 2.07 results DFT‐based calculations involving new implementation bifunctional formalism for exchange energy. By treatment 0.1 molar hydrochloric acid, AlCl leached yielding compound presumed composition )Cl. Hydrolysis higher pH resulted Cu 2–x O 5 Cl .
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ژورنال
عنوان ژورنال: Zeitschrift für anorganische und allgemeine Chemie
سال: 2022
ISSN: ['0044-2313', '1521-3749']
DOI: https://doi.org/10.1002/zaac.202200021